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作为变质核杂岩构造的重要组成部分,拆离断层带内广泛发育的褶皱构造与其寄主岩石一样记录了中下地壳拆离作用过程。选取辽南变质核杂岩金州拆离断层带内褶皱构造作为研究对象,基于叶理与褶皱构造关系分析,划分了褶皱期次与阶段性;通过形态组构分析、结晶学组构分析及石英古温度计等技术方法的应用,初步分析了拆离断层内褶皱的形成机制,为辽南地区拆离作用过程提供约束。根据褶皱形成与拆离作用的时间关系,将拆离带内褶皱分为拆离前褶皱、拆离同期褶皱和拆离后褶皱;拆离作用同期的褶皱按时间早晚分为早期(a1)阶段、中期(a2)阶段、晚期(a3)阶段。不同阶段褶皱的野外形态、叶理与褶皱关系等方面的差异,以及形态组构与结晶学组构的特征,为判断和恢复褶皱的形成机制提供了佐证,揭示出拆离断层带褶皱是在纵弯压扁和顺层流变的共同作用下递进剪切变形的产物。在拆离作用过程中, a1阶段和a2阶段褶皱以纵弯、压扁褶皱作用为主,a3阶段褶皱以弯滑作用为主。褶皱作用记录了拆离断层一定温度范围内(主要集中在380~500 ℃)的变形特征,拆离作用从早期到晚期的演化整体处于相对稳定的应变状态下。对金州拆离断层带而言,在区域NW-SE向伸展过程中,还伴随着NE-SW向微弱的收缩。 相似文献
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The possibility of recrystallization is a long‐standing barrier to deciphering the genetic origin of dolomites. There is often uncertainty regarding whether or not characteristics of ancient dolomites are primary or the consequence of later recrystallization unrelated to the original dolomitization event. Results from 65 new high‐temperature dolomite synthesis experiments (1 m , 1·0 Mg/Ca ratio solutions at 218°C) demonstrate dolomite recrystallization affecting stoichiometry, cation ordering and nanometre‐scale surface texture. The data support a model of dolomitization that proceeds by a series of four unique phases of replacement and recrystallization, which occur by various dissolution–precipitation reactions. During the first phase (induction period), no dolomite forms despite favourable conditions. The second phase (replacement period) occurs when Ca‐rich dolomite products, with a low degree of cation ordering, rapidly replace calcite reactants. During the replacement period, dolomite stoichiometry and the degree of cation ordering remain constant, and all dolomite crystal surfaces are covered by nanometre‐scale growth mounds. The third phase (primary recrystallization period), which occurs in the experiments between 97% and 100% dolomite, is characterized by a reduced replacement rate but concurrent increases in dolomite stoichiometry and cation ordering. The end of the primary recrystallization period is marked by dolomite crystal growth surfaces that are covered by flat, laterally extensive layers. The fourth phase of the reaction (secondary recrystallization period) occurs when all calcite is consumed and is characterized by stoichiometric dolomite with layers as well as a continued increase in the degree of cation ordering with time. Inferences of recrystallization, in natural dolomite, based on cation order or stoichiometry of dolomite, usually depend on assumptions about the precursor dolomite subjected to recrystallization. If it is assumed that the experimental evidence presented here is applicable to natural, low‐temperature dolomites, then the presence of mounds is direct evidence of a lack of recrystallization and the presence of layers is direct evidence of recrystallization. 相似文献
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研究了N甲基对二甲胺基苯乙烯吡啶碘盐系列化合物的合成、分离方法,通过可见吸收、MS谱、HNMR 谱及氮素测定分析产物,证实了其结构和理论预期的一致性 相似文献
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The formation and subsequent reactions of magnesiancalcite overgrowths on calcite were investigated bymeans of closed system seeded precipitationexperiments. These experiments demonstrated that(1) thin overgrowths of magnesian calcite are precipitatedon calcite seeds suspended in seawater;(2) the solubilities of the coatings increase outward from theseed crystals as a linear function of the log ofrelative coating thickness;(3) during the period ofthese experiments (up to 5.5 months), the magnesiancalcite coatings continued to increase in thickness,but became less soluble in composition. Thestabilization reaction, referred to asrecrystallization, can be described by the followingequation:Cax Mg(1-x) CO3 + [z + y(x + z)]Ca2++ 2yHCO3- ]= (1 + y)Ca(x + z)Mg(1 - x -z)CO3 + [z + y(x + z - 1)]Mg2++ y CO2 + yH20;]4) recrystallization rate is dependent on solutionsaturation state, with a reaction order of 3.2 forartificial seawater and 4.0 for natural seawater; and(5) by the cessation of the closed system experiments,overgrowth compositions approached that of the stablecalcite (a few mol % MgCO3).Armoring of suspended carbonate particles in thesurface oceans with magnesian calcite overgrowthswould provide an effective barrier to release of theoceanic supersaturation with respect to calcite. Thicknesses of such coatings would be limited by therecrystallization rate of the magnesian calcite. Estimates based on the recrystallization ratesdetermined in this work indicate coatings on the orderof 0.02 µm in thickness could form on particles asthey sink through the mixed layer. According to thesecalculations, the total amount of carbon precipitatedannually in magnesian calcite overgrowths iscomparable to the riverine flux of dissolved carbon tothe oceans. Field observations of severalinvestigators indicate the likely presence ofmagnesian calcite coatings on planktonic particles,and provide evidence for possible recrystallization ofbiogenic magnesian particles in the marineenvironment. 相似文献
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葛建华 《沉积与特提斯地质》2009,29(4):96-99
在使用全谱直读等离子体发射光谱仪分析铅时,发现Cu221.810线对Pb220.3线形成干扰。产生这种干扰的原因是由于全谱直读等离子体发射光谱仪采用了固态阵列检测器和中阶梯光栅,从而在两条谱带之间发生了纵向干扰校正。可以采用干扰系数校正法或者选择在灵敏度稍低的VIS段摄谱进行干扰。 相似文献
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The effect of fluids on recrystallization behaviour is well known; however, the detailed microscale distribution of fluid in grain boundaries and the influence of fluid on grain boundary migration are still unresolved. In this study, in‐situ deformation experiments in transmitted light microscopy were undertaken, as this allows continuous and direct observation of the whole range of processes involved in fluid‐assisted grain boundary migration. A new see‐through deformation apparatus was developed to enable the control of fluid pressure. Bischofite containing small amounts of aqueous fluid was deformed at temperatures between 50 and 90 °C, over a range of fluid pressure from 0.5 to 1 MPa, and strain rates of 5 × 10?6 to 1 × 10?4 s?1. The rates of grain boundary migration were measured at different temperatures and strain rates. Detailed observations during and after the deformation illustrate the evolution of migrating fluid‐filled grain boundaries and show that the incorporation of fluids from inclusions as well as their pinch‐off is dependent on the grain boundary velocity, the thickness of the grain boundary and the size and shape of the inclusions. Direct evidence is presented for the contraction of the grain boundary fluids into isolated inclusions after equilibrium conditions are attained. 相似文献